Instead of simply identifying some small gap in the popular literature, Thinking, Fast and Slow is essentially a grand synthesis of behavioral psychology and economics: Nassim Taleb's focus on randomness and biases in epistemology (The Black Swan), Roy Baumeister's research into self-control (Willpower), Ian Ayres' thoughts on intuition and expertise (Super Crunchers), Cass Sunstein's theories on risk assessment (Risk and Reason), and Richard Thaler's conclusions about the normative implications for public policy (Nudge) all receive attention. Kahneman weaves these aspects together with storytelling, experimental accounts, and interactive games to articulate one simple theory: that human decisionmaking is governed by two systems, one fast, emotional, and unconscious, the other slow, calculating, and deliberate. Even with a high level of familiarity with these topics, Thinking, Fast and Slow is a great book to read, if only because it's written by the master himself. The few biographical bits scattered throughout the book are really interesting, describing Kahneman's work as a young psychologist working for the Israeli military.
Check out a great interview with Kahneman here, his fantastic TED Talk here, and a superb book review by the great Freeman Dyson here.